The electronic absorption spectrum of chromate ion

被引：84

作者：

Johnson, L. W. ^{[1
]}

McGlynn, S. P. ^{[1
]}

机构：

[1] Louisiana State Univ, Coales Chem Labs, Baton Rouge, LA 70803 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 06期

关键词：

D O I：

10.1016/0009-2614(70)87021-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electronic spectrum of CrO42- is identical to that of MnO4- except for an energy inversion of the 3rd and 4th band systems. A very weak lowest-energy band, the authenticity of which has been in debate for MnO4- is unambiguously present in CrO42-. The intense (is an element of approximate to 10(4)) 55 560 cm(-1) band of CrO42- and the correlating 52 600 cm(-1) band of MnO4- exhibit a significant decrease of intensity in the solid state; the corresponding transitions presumably possess "big orbit" character.

引用

页码：618 / 620

页数：3

共 13 条

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