INDEPENDENT GENERATION OF THE MAJOR ADDUCT OF HYDROXYL RADICAL AND THYMIDINE - EXAMINATION OF INTRAMOLECULAR HYDROGEN-ATOM TRANSFER IN COMPETITION WITH THIOL TRAPPING

被引：12

作者：

BARVIAN, MR ^{[1
]}

GREENBERG, MM ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)60005-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

5,6-Dihydro-5-hydroxythymid-6-yl (1) has been generated from 2 via photoinduced electron transfer from N-methylcarbazole. In agreement with prior reports, deuterium incorporation in conjunction with H-2 NMR analysis of 5,6-dihydro-5-hydroxythymidine (3) formed from 1 provides no evidence for intramolecular hydrogen atom abstraction.

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页码：6057 / 6060

页数：4

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