A NEW PREPARATION OF LANTHANIDE ALKOXIDES, AND SOME APPLICATIONS IN CATALYSIS

被引：77

作者：

LEBRUN, A ^{[1
]}

NAMY, JL ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,SYNTH ASYMETR LAB,CNRS,URA 255,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 21期

关键词：

PREPARATION OF LANTHANIDE ALKOXIDES; LANTHANIDE CHLORIDES; CATALYSTS; EPOXIDATION; MEERWEIN-PONNDORF-VERLEY-OPPENAUER REACTIONS;

D O I：

10.1016/S0040-4039(00)79922-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new route to lanthanide tris(alkoxides) is described. These compounds are easily prepared by reaction of n-BuLi with corresponding adducts LnCl3, (3-4 ROH) that are obtained from hydrated LnCl3. They are efficient as catalysts in epoxidation of allylic alcohols by TBHP and in Meerwein-Ponndrof-Verley-Oppenauer reactions.

引用

页码：2355 / 2358

页数：4

共 7 条

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EVANS, DA
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[6] NEW PREPARATIONS OF LANTHANIDE ALKOXIDES AND THEIR CATALYTICAL ACTIVITY IN MEERWEIN-PONNDORF-VERLEY-OPPENAUER REACTIONS
NAMY, JL
SOUPPE, J
COLLIN, J
KAGAN, HB
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (11) : 2045 - 2049
[7] MEERWEIN-PONNDORF-VERLEY REDUCTION OF KETONES AND ALDEHYDES CATALYZED BY LANTHANIDE TRI-2-PROPOXIDES
OKANO, T
MATSUOKA, M
KONISHI, H
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[J]. CHEMISTRY LETTERS, 1987, (01) : 181 - 184

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