COMPARATIVE-STUDIES ON THE GENERATION AND CYCLIZATION REACTIONS OF DIFLUOROALKYL RADICALS

被引：32

作者：

BUTTLE, LA

MOTHERWELL, WB

机构：

[1] UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(00)76723-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of a series of unsaturated bromodifluoromethyl malonate precursors using organotin, samarium, and cobalt reagents as radical triggers leads to the formation of usefully functionalised fluorinated cyclopentanoid products,

引用

页码：3995 / 3998

页数：4

共 20 条

[1] SYNTHESIS OF THE 2 ENANTIOMERS OF 1-CHLORO-1,1-DIFLUORO-3-(PARA-TOLYLSULPHONYL)PROPAN-2-OL BY MICROBIAL REDUCTION OF THE PARENT PROPANONE AND TRANSFORMATION INTO 3,3-DIFLUOROTETRAHYDROFURAN DERIVATIVES
ARNONE, A
BERNARDI, R
BRAVO, P
CARDILLO, R
GHIRINGHELLI, D
CAVICCHIO, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (08): : 1887 - 1891
[2] CYCLIZATION OF ALPHA,ALPHA-DIFLUOROMETHYL RADICALS - A NEW ROUTE TO THE PREPARATION OF DIFLUOROCYCLOPENTANE DERIVATIVES
BARTH, F
OYANG, C
[J]. TETRAHEDRON LETTERS, 1991, 32 (42) : 5873 - 5876
[3] AN IMPROVED RADICAL CHAIN PROCEDURE FOR THE DEOXYGENATION OF SECONDARY AND PRIMARY ALCOHOLS USING DIPHENYLSILANE AS HYDROGEN-ATOM DONOR AND TRIETHYLBORANE-AIR AS INITIATOR
BARTON, DHR
JANG, DO
JASZBERENYI, JC
[J]. TETRAHEDRON LETTERS, 1990, 31 (33) : 4681 - 4684
[4] SAMARIUM(II) IODIDE PROMOTED RADICAL RING-OPENING REACTIONS OF CYCLOPROPYL KETONES
BATEY, RA
MOTHERWELL, WB
[J]. TETRAHEDRON LETTERS, 1991, 32 (43) : 6211 - 6214
[5] NEW SYNTHETIC METHODS VIA FREE-RADICALS - FREE-RADICAL GENERATION VIA PHOTOLYTIC HOMOLYSIS OF ALKYL-COBALOXIME C-CO BONDS - EFFICIENT RADICAL TRAPPING WITH USEFUL FUNCTIONAL-GROUPS
BRANCHAUD, BP
MEIER, MS
MALEKZADEH, MN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (02) : 212 - 217
[6] ORGANOSILANES AS RADICAL-BASED REDUCING AGENTS IN SYNTHESIS
CHATGILIALOGLU, C
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (04) : 188 - 194
[7] THE DESIGN AND APPLICATION OF FREE-RADICAL CHAIN REACTIONS IN ORGANIC-SYNTHESIS .1.
CURRAN, DP
[J]. SYNTHESIS-STUTTGART, 1988, (06): : 417 - 439
[8] THE DESIGN AND APPLICATION OF FREE-RADICAL CHAIN REACTIONS IN ORGANIC-SYNTHESIS .2.
CURRAN, DP
[J]. SYNTHESIS-STUTTGART, 1988, (07): : 489 - 513
[9] GIESE B, 1992, TETRAHEDRON LETT, V32, P4545
[10] Giese B., 1986, RADICALS ORGANIC SYN

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