STRUCTURAL STUDY OF RECOGNIZABLE ADENINE AND THYMINE NUCLEOBASES FUNCTIONALIZED WITH LONG ALIPHATIC CHAINS

被引：12

作者：

MICHAS, J ^{[1
]}

PALEOS, CM ^{[1
]}

SKOULIOS, A ^{[1
]}

WEBER, P ^{[1
]}

机构：

[1] INST PHYS & CHIM MAT STRASBOURG,MAT ORGAN GRP,STRASBOURG,FRANCE

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1994年 / 239卷

关键词：

MOLECULAR RECOGNITION; AMPHIPHILIC-LIKE ADENINE AND THYMINE NUCLEOBASES; HYDROGEN BONDING;

D O I：

10.1080/10587259408047186

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A series of complementary adenine and thymine alkyl derivatives were synthesized and characterized. Due to their amphiphilic-like chemical structure, these compounds, either in a pure state or in binary mixtures, form well developed lamellar structures from room temperature up to the clearing point. Hydrogen bonding between the recognizable moieties are responsible for the increased stability of the crystalline forms. The absence of stable liquid crystalline phases may also be attributed to the unfavorable shape of the alkylated nucleobases and of their complexes.

引用

页码：245 / 255

页数：11

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