REACTIONS OF PENTAFLUOROPHENYLCOPPER REAGENT

被引：61

作者：

DEPASQUALE, RJ

TAMBORSKI, C

机构：

[1] Air Force Materials Laboratory, Nonmetallic Materials Division, Ohio 45483, Wright-Patterson Air Force Base

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 06期

关键词：

D O I：

10.1021/jo01258a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A pentafluorophenylcopper reagent containing magnesium halide was prepared from the reaction between pentafluorophenylmagnesium bromide and cuprous chloride. The reagent underwent reactions representative of both organocopper and perfluoroaryl organometallic compounds. Reactions with H2O, CO2, O2, C3H6I, p-C6F5OC6F4Br, p-CH3OC6F4J, CF2=CFI, and C7F16I have been studied. The effect of the magnesium halide content on the reactivity of the pentafluorophenylcopper reagent was examined. © 1969, American Chemical Society. All rights reserved.

引用

页码：1736 / +

页数：1

共 28 条

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