FERROCENYL CARBOCATIONS - STABILITY OF SOME [4]FERROCENOPHANE 6-CARBOCATIONS AND 7-CARBOCATIONS

被引：16

作者：

ORTAGGI, G

RICCIO, P

TRITTO, I

机构：

[1] Centro C.N.R. dei Meccanismi di Reazione, c/o Istituto di Chimica Orgánica, Universitá di Roma

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 16期

关键词：

D O I：

10.1021/jo01330a020

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The equilibrium constants for the protonation of [4]ferrocenophan-7-one and-6-one and for the ionization of the corresponding alcohols in aqueous sulfuric acid, as well as the behavior of these molecules as acid-base indicators, suggest that the [4]ferrocenophane 7-carbocations are strongly stabilized by the ferrocenyl group, despite the distance of the positive center from the Cp ring. © 1979, American Chemical Society. All rights reserved.

引用

页码：2920 / 2923

页数：4

共 20 条

[1] BRIDGED FERROCENES .2. CONFORMATIONAL PROPERTIES OF [M]FERROCENOPHANES [J].