HIGHLY THREO-SELECTIVE ENE-REACTION OF 2-(ALKYLTHIO)ALLYL SILYL ETHERS WITH ALDEHYDES

被引：24

作者：

TANINO, K ^{[1
]}

NAKAMURA, T ^{[1
]}

KUWAJIMA, I ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 15期

关键词：

D O I：

10.1016/0040-4039(90)80099-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under the influence of Mc2A1C1, ene-reaction of 2-(alkylthio)allyl silyl ethers readily proceeds with a wide range of aldehydes to afford the corresponding γ-hydroxy carbonyl compounds as their enol silyl ethers with high threo-preference as well as excellent (Z)-selectivity. © 1990.

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页码：2165 / 2168

页数：4

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