PHOTOCHEMISTRY OF PYRIDINIUM SALTS .1. INTRAMOLECULAR CHARGE-TRANSFER IN N-AMINO-SUBSTITUTED PYRIDINIUM CATIONS

被引：3

作者：

FEYGELMAN, VM

TYMYANSKII, YR

MAKAROVA, NI

KNYAZHANSKII, MI

DRUZHININ, SI

UZHINOV, BM

机构：

[1] ROSTOV DON STATE UNIV,INST PHYS & ORGAN CHEM,ROSTOV 344104,USSR

[2] MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,USSR

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1990年 / 3卷 / 03期

关键词：

D O I：

10.1002/poc.610030310

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photophysics and photochemistry of N‐amino‐substituted pyridinium salts were investigated. Electron transfer from the amino group to the pyridinium ring takes place in the singlet excited state. The fluorescence quenching and photoreactivity of these compounds is conditioned by this process. Irradiation of N‐aminopyridinium salts in solution leads to novel fused heterocycles or to triphenylpyridine, depending on the concentration of the initial compound. Free radical intermediates are involved in the photoreaction. Copyright © 1990 John Wiley & Sons Ltd.

引用

页码：200 / 204

页数：5

共 13 条

[1]

ALDER RW, 1982, CHEM FUNCTIONAL G SF, P763

[2]

BALABHAN AT, 1982, ADV HETEROCYCLIC C S, V2, P114

[3] USE OF CNDO METHOD IN SPECTROSCOPY .3. MONOSUBSTITUTED BENZENES AND PYRIDINES [J].