SUPPORTED REDOX PHOTOSENSITIZERS FOR THE ACTIVATION OF ALKYLAROMATICS TOWARDS OXYGEN

被引:18
作者
JULLIARD, M
LEGRIS, C
CHANON, M
机构
[1] Laboratoire SM3B, associé au CNRS URA 1411, Faculté des Sciences et Techniques Saint Jérome
关键词
D O I
10.1016/1010-6030(91)85082-R
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Several 2,4,6-trinitrobenzene derivatives and 2,4,7-trinitrofluorenone were grafted on silica and used as supported electron-acceptor photosensitizers. The grafting was effected by two methods: reaction of a halogenated derivative with aminopropyl silica or condensation on silica of the electron acceptor previously transformed into monochlorosilane. The oxidation of 4-methyl anisole by redox photosensitization was used as a test reaction to compare the efficiencies of these heterogeneous photosensitizers. Silica grafted 2,4,6-trinitrobenzene was then used to oxidize 4-substituted methyl aromatic compounds into the corresponding aromatic aldehydes with 76%-90% yields and 100% selectivity.
引用
收藏
页码:137 / 152
页数:16
相关论文
共 84 条
[1]   POLY(ETHYLENE-TEREPHTHALATE) AS AN INSOLUBLE ELECTRON-TRANSFER PHOTOSENSITIZER [J].
ALBINI, A ;
SPRETI, S .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (18) :1426-1427
[2]  
ALBINI A, 1986, Z NATURFORSCH, V416, P1286
[3]   POLY(PARA-(TRIFLUOROVINYL)BENZOPHENONE) AND POLY(PARA-(TRIFLUOROVINYL)ACETOPHENONE) - PHOTOSTABLE POLYMERIC TRIPLET ENERGY-TRANSFER DONORS [J].
ASAI, N ;
NECKERS, DC .
JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (14) :2903-2907
[4]  
BERTRANDMOTARD C, 1987, THESIS U BORDEAUX
[5]   POLYMER-BASED SENSITIZERS FOR PHOTOOXIDATIONS [J].
BLOSSEY, EC ;
NECKERS, DC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (17) :5820-5822
[6]  
BLOSSEY EC, 1974, TETRAHEDRON LETT, V15, P323
[7]   THE USE OF INSOLUBLE BENZOYLATED POLYSTYRENE BEADS (POLYMERIC BENZOPHENONE) IN PHOTOCHEMICAL-REACTIONS [J].
BOURDELANDE, JL ;
FONT, J ;
SANCHEZFERRANDO, F .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1983, 61 (05) :1007-1016
[8]   TRANSIENT-BEHAVIOR AND LUMINESCENCE QUENCHING OF RU(BPY)3(2+) BOUND TO AN INSOLUBLE POLYMERIC PHASE [J].
BOURDELANDE, JL ;
CAMPA, C ;
CAMPS, J ;
FONT, J ;
DEMARCH, P ;
WILKINSON, F ;
WILLSHER, CJ .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1988, 44 (01) :51-55
[9]   PHOTOCYCLOADDITION OF CYCLOHEXENE AND MALEIC-ANHYDRIDE SENSITIZED BY INSOLUBLE BENZOYLATED POLYSTYRENE [J].
BOURDELANDE, JL ;
FONT, J ;
SANCHEZFERRANDO, F .
TETRAHEDRON LETTERS, 1980, 21 (39) :3805-3808
[10]   SPECTROSCOPIC PROPERTIES AND PHOTOCHEMICAL BEHAVIOR OF POLYMERS WITH COVALENTLY BOUND TRIS(BIPYRIDINE)RUTHENIUM(II) COMPLEX - USE OF A HYDROPHILIC CHAIN AS SPACER [J].
BOURDELANDE, JL ;
CAMPA, C ;
FONT, J ;
DEMARCH, P .
EUROPEAN POLYMER JOURNAL, 1989, 25 (02) :197-202