SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF CYCLOOCTATETRAENYLLANTHANIDE ALKYL COMPLEXES [LI(THF)2(MU-(ETA-2-ETA-8-C8H8))LN(CH(SIME3)2)2] (LN = Y, SM, LU THF = TETRAHYDROFURAN)

被引：23

作者：

SCHUMANN, H

WINTERFELD, J

GORLITZ, FH

PICKARDT, J

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 07期

关键词：

D O I：

10.1039/c39930000623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metathetic reaction [Ln(eta8-C8H8)(mu-Cl)(thf)]2 (Ln = Y, Sm, Lu) with LiCH(SiMe3)2 results in the formation of the cyclooctatetraenyllanthanide alkyl complexes [Li(thf)2{mu-(eta2:eta8-C8H8)}Ln{CH(SiMe3)2}2] (Ln = Y la, Sm lb, Lu 1c); lb has been structurally characterized by X-ray crystallography.

引用

收藏

页码：623 / 625

页数：3

相关论文

共 28 条

[1] ON THE SYNTHESIS OF MONOPENTAMETHYLCYCLOPENTADIENYL DERIVATIVES OF YTTRIUM, LANTHANUM, AND CERIUM [J].

BOOIJ, M ;

KIERS, NH ;

HEERES, HJ ;

TEUBEN, JH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 364 (1-2) :79-86

[2] STRUCTURES OF ORGANO-F-ELEMENT COMPOUNDS DIFFERING IN THE OXIDATION-STATE OF THE CENTRAL METAL - CRYSTAL-STRUCTURES OF BIS([8]ANNULENE) COMPLEXES OF CERIUM(IV), YTTERBIUM(III), AND URANIUM(III) [J].

BOUSSIE, TR ;

EISENBERG, DC ;

RIGSBEE, J ;

STREITWIESER, A ;

ZALKIN, A .

ORGANOMETALLICS, 1991, 10 (06) :1922-1928

[3] MIXED SANDWICHES OF GROUP-3 ELEMENTS - SYNTHESIS AND UPS STUDIES OF PENTAMETHYLCYCLOPENTADIENYLCYCLOOCTATETRAENE-SCANDIUM, YTTRIUM AND LANTHANUM [J].

BRUIN, P ;

BOOIJ, M ;

TEUBEN, JH ;

OSKAM, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 350 (01) :17-23

[4] ELECTRONIC-STRUCTURE AND SPECTRA OF URANOCENE [J].

CHANG, AHH ;

PITZER, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) :2500-2507

[5] MONO(PENTAMETHYLCYCLOPENTADIENYL) COMPLEXES OF CERIUM(III) - SYNTHESIS, MOLECULAR-STRUCTURE, THERMAL-STABILITY, AND REACTIVITY OF (C5ME5)CEX2 (X = 2,6-DI-TERT-BUTYLPHENOXO, CH(SIME3)2, AND N(SIME3)2) COMPLEXES [J].

HEERES, HJ ;

MEETSMA, A ;

TEUBEN, JH ;

ROGERS, RD .

ORGANOMETALLICS, 1989, 8 (11) :2637-2646

[6] ION-PAIR COMPLEX FORMED BETWEEN BIS(CYCLOOCTATETRAENYL)CERIUM(III) ANION AND AN ETHER-COORDINATED POTASSIUM CATION - CRYSTAL AND MOLECULAR STRUCTURE OF [K)(CH3OCH2CH2)2O)[]CE(C8H8)2] [J].

HODGSON, KO ;

RAYMOND, KN .

INORGANIC CHEMISTRY, 1972, 11 (12) :3030-&

[7] LANTHANIDE(III) COMPLEXES WITH CYCLOOCTATETRAENE DIANION - SYNTHETIC CHEMISTRY, CHARACTERIZATION, AND PHYSICAL-PROPERTIES [J].

HODGSON, KO ;

MARES, F ;

STARKS, DF ;

STREITWIESER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (26) :8650-8658

[8]

JAMMERSON JD, 1974, J ORGANOMET CHEM, V65, pC33

[9]

JOHNSON CK, 1976, ORNL5138 REP

[10]

MARES F, 1970, J ORGANOMET CHEM, V24, pC68