HYDROGENOLYSIS OF PROPANE ON SUPPORTED CATALYSTS OF NICKEL, COBALT, IRON, AND RUTHENIUM

被引：40

作者：

MACHIELS, CJ

ANDERSON, RB

机构：

[1] MCMASTER UNIV,DEPT CHEM ENGN,HAMILTON L8S 4L8,ONTARIO,CANADA

[2] MCMASTER UNIV,INST MAT RES,HAMILTON L8S 4L8,ONTARIO,CANADA

来源：

JOURNAL OF CATALYSIS | 1979年 / 58卷 / 02期

关键词：

D O I：

10.1016/0021-9517(79)90262-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenolysis of propane was studied in a differential reactor system over supported catalysts of ruthenium, nickel, cobalt, and iron, some containing magnesia as a structural promoter. The kinetic data were fitted to a power rate equation. The results are in general agreement with those of similar experiments with ethane. Magnesia increased the activity of the nickel and cobalt catalysts, and stabilized the iron catalyst. Selectivities for ethane were fitted to a selectivity equation. The amount of ethane in the products decreased in the sequence: ruthenium, cobalt, nickel, iron. © 1979.

引用

页码：253 / 259

页数：7

共 14 条

[1] STUDIES OF THE FISCHER-TROPSCH SYNTHESIS .9. PHASE CHANGES OF IRON CATALYSTS IN THE SYNTHESIS [J].