FACTORS AFFECTING FORMATION AND STABILITY OF EQUILIBRATING PROTONATED CYCLOPROPANE

被引：11

作者：

FRIEDMAN, L

JUREWICZ, A

机构：

[1] Department of Chemistry, Case Western Reserve University, Cleveland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 07期

关键词：

D O I：

10.1021/ja01035a033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deamination of n-propyl-3,3,3-d3-amine and n-propyl-2,2-d2-amine gave hydrocarbon mixtures containing cyclopropane and propene. The deuterium content of the cyclopropane varied with the reaction medium and this is attributed to solvent dependency on the extent of equilibration of the intermediate protonated cyclopropane. Routes for propene formation are also suggested. © 1969, American Chemical Society. All rights reserved.

引用

页码：1800 / &

共 32 条

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