SYNTHESIS AND PROPERTIES OF ALKOXYALKYLIDINE-TRICOBALT NONACARBONYL CLUSTER COMPLEXES

被引：22

作者：

MIGNANI, G

PATIN, H

DABARD, R

机构：

[1] Laboratoire de Chimie des Organométalliques, ERA CNRS No. 477, Université de Rennes, 35042 Rennes Cedex, Campus de Beaulieu

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 169卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81468-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds are obtained in fair to good yield by desulfurization of S-alkyl xanthates in reactions with dicobalt octacarbonyl. The cluster structure is supported by mass spectroscopic and NMR data, and evidence is presented for an elimination step leading to desulfurization. These air-stable complexes are active catalysts for hydroformylation of olefins. © 1979.

引用

页码：C19 / C21

页数：3