THE STRUCTURE OF A COPPER(I)-SCHIFF BASE COMPLEX [CUN(CH2CH2N=CH-C6H5)3]+[BPH4]-

被引：20

作者：

ALYEA, EC

FERGUSON, G

JENNINGS, MC

XU, Z

机构：

[1] Department of Chemistry and Biochemistry, University of Guelph, Guelph

来源：

POLYHEDRON | 1990年 / 9卷 / 05期

关键词：

D O I：

10.1016/S0277-5387(00)80283-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A crystal structure analysis of [CuN(CH2CH2NCHC6H5)3]+[BPh4]- reveals that the complex has approximate three-fold symmetry in the solid state with the copper(I) atom having trigonal-pyramidal geometry. Principal dimensions are CuN (apical) 2.232(2), CuN(equatorial) 2.004, 2.006 and 2.019(2) Å, N(ap)CuN(eq) 83.7-84.6(1)°. The CuH distances to the ortho-phenyl hydrogen atoms are too long to be considered agostic. The 1H NMR spectrum is consistent with a similar structure for the copper(I) cation complex in solution. © 1990.

引用

页码：739 / 741

页数：3

共 8 条

[1] STRUCTURE OF A POTENTIALLY HEPTADENTATE TRIPODAL LIGAND, TRIS[4-(2-THIENYL)-3-AZA-3-BUTENYL]AMINE [J].