ON THE LEAST-SQUARES FITTING OF CORRELATED DATA - REMOVING THE CORRELATION

被引:10
作者
TELLINGHUISEN, J
机构
[1] Department of Chemistry, Vanderbilt University, Nashville
关键词
D O I
10.1006/jmsp.1994.1127
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
In the most general case of linear least-squares fitting, the input data may be mutually correlated. This correlation is accommodated through a weight matrix W which contains off-diagonal elements. The existence of strong correlation in the data makes it difficult to interpret the fit residuals in terms of ''good'' and ''bad'' data. However, it is possible to transform the original correlated problem into an equivalent uncorrelated, unweighted fit through a simple linear transformation. This transformation is readily obtained from the orthogonal transformation which diagonalizes W. (C) 1994 Academic Press, Inc.
引用
收藏
页码:255 / 264
页数:10
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