CHARACTERISTICS OF A LITHIUM SECONDARY BATTERY USING CHEMICALLY-SYNTHESIZED CONDUCTIVE POLYMERS

被引：56

作者：

NISHIO, K ^{[1
]}

FUJIMOTO, M ^{[1
]}

YOSHINAGA, N ^{[1
]}

FURUKAWA, N ^{[1
]}

ANDO, O ^{[1
]}

ONO, H ^{[1
]}

SUZUKI, T ^{[1
]}

机构：

[1] MITSUBISHI KASEI CORP,RES CTR,MIDORI KU,YOKOHAMA 227,JAPAN

来源：

JOURNAL OF POWER SOURCES | 1991年 / 34卷 / 02期

关键词：

D O I：

10.1016/0378-7753(91)85035-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several conductive polymers (polyacetylene, polypyrrole, polythiophene, polyiminodibenzyl, polycarbazole, polyfuran, polyphenothiazine) have been synthesized by a chemical polymerization method and examined for their suitability as positive electrode material for lithium secondary batteries. A test cell, using polypyrrole as a positive electrode, showed good charge/discharge characteristics. Oxidizing agents for the synthesis of polypyrrole have been investigated for further improvement, and polypyrrole prepared by a new method of synthesis using a Cu(BF4)2/nitrile system exhibited excellent performance.

引用

页码：153 / 160

页数：8

共 9 条

[1] POLYACETYLENE ELECTRODES FOR NON-AQUEOUS LITHIUM BATTERIES [J].

FARRINGTON, GC ;

HUQ, R .

JOURNAL OF POWER SOURCES, 1985, 14 (1-3) :3-9

[2] A RECHARGEABLE BATTERY OF THE TYPE POLYANILINE PROPYLENE CARBONATE - LICLO4 - LI-AL [J].

GENIES, EM ;

HANY, P ;

SANTIER, C .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1988, 18 (05) :751-756

[3] A NEW ELECTRODE-ACTIVE MATERIAL FOR POLYMER BATTERIES - POLYVINYLFERROCENE [J].

IWAKURA, C ;

KAWAI, T ;

NOJIMA, M ;

YONEYAMA, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (04) :791-794

[4] POLYTHIENOTHIOPHENE AS CATHODE ACTIVE MATERIAL - A COMPARATIVE-STUDY WITH POLYTHIOPHENE AND POLYDITHIENOTHIOPHENE [J].

MASTRAGOSTINO, M ;

MARINANGELI, AM ;

CORRADINI, A ;

ARBIZZANI, C .

ELECTROCHIMICA ACTA, 1987, 32 (11) :1589-1593

[5] LIGHTWEIGHT RECHARGEABLE STORAGE BATTERIES USING POLYACETYLENE, (CH)X AS THE CATHODE-ACTIVE MATERIAL [J].

NIGREY, PJ ;

MACINNES, D ;

NAIRNS, DP ;

MACDIARMID, AG ;

HEEGER, AJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (08) :1651-1654

[6]

OBAYASHI K, 1987, SYNTHETIC MET, V18, P365

[7] DEPENDENCE OF FILM THICKNESS ON ELECTROCHEMICAL KINETICS OF POLYPYRROLE AND ON PROPERTIES OF LITHIUM-POLYPYRROLE BATTERY [J].

OSAKA, T ;

NAOI, K ;

OGANO, S ;

NAKAMURA, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (09) :2096-2102

[8] ELECTROCHEMICAL CHARACTERISTICS OF POLYACETYLENE IN ORGANIC ELECTROLYTES [J].

PADULA, A ;

SCROSATI, B .

JOURNAL OF POWER SOURCES, 1985, 14 (1-3) :31-38

[9] INFRARED SPECTRA OF POLY(ACETYLENE) [J].

SHIRAKAWA, H ;

IKEDA, S .

POLYMER JOURNAL, 1971, 2 (02) :231-+

← 1 →