ANALYTIC FORM FOR THE NONRELATIVISTIC COULOMB PROPAGATOR

被引:26
作者
BLINDER, SM
机构
[1] Department of Chemistry, University of Michigan, Ann Arbor
来源
PHYSICAL REVIEW A | 1991年 / 43卷 / 01期
关键词
D O I
10.1103/PhysRevA.43.13
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
An analytic form for the nonrelativistic Coulomb propagator is derived, thus resolving a long-standing problem in Feynman's path-integral formulation of quantum mechanics. Hostler's formula for the Coulomb Green's function is expanded according to the theorem of Mittag-Leffler, then Fourier transformed term by term to give the Coulomb propagator. The result is a discrete summation over the principal quantum number n, involving Whittaker, Laguerre, Hermite, and error functions. As is the case for other nonquadratic potentials, the Coulomb propagator does not have the canonical structure K = F exp(iS/h). Part of the expansion resembles a form derived by Crandall [J. Phys. A 16, 3005 (1983)] for the case of reflectionless potentials.
引用
收藏
页码:13 / 16
页数:4
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