HIGH ASYMMETRIC INDUCTION IN THE CHIRAL HYDROBORATION OF TRANS ALKENES WITH ISOPINOCAMPHEYLBORANE - EVIDENCE FOR A STRONG STERIC DEPENDENCE IN SUCH ASYMMETRIC HYDROBORATIONS

被引：24

作者：

BROWN, HC

JADHAV, PK

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1981年 / 46卷 / 24期

关键词：

D O I：

10.1021/jo00337a060

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

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页码：5047 / 5048

页数：2

相关论文

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[2] HYDROBORATION .19. REACTION OF DIISOPINOCAMPHEYLBORANE WITH REPRESENTATIVE TRANS + HINDERED OLEFINS ( TRIISOPINOCAMPHEYLDIBORANE AS REAGENT FOR CONFIGURATIONAL ASSIGNMENT OF ALCOHOLS + OLEFINS VIA HYDROBORATION
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[3] MONOISOPINOCAMPHEYLBORANE - NEW CHIRAL HYDROBORATING AGENT FOR RELATIVELY HINDERED (TRISUBSTITUTED) OLEFINS
BROWN, HC
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[4] HYDROBORATION .18. REACTION OF DIISOPINOCAMPHEYLBORANE WITH REPRESENTATIVE CIS-ACYCLIC CYCLIC + BICYCLIC OLEFINS . CONVENIENT SYNTHESIS OF OPTICALLY ACTIVE ALCOHOLS + OLEFINS OF HIGH OPTICAL PURITY + ESTABLISHED CONFIGURATION
BROWN, HC
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[5] BROWN HC, 1961, J AM CHEM SOC, V83, P486, DOI 10.1021/ja01463a055
[6] SIMPLE SYNTHESIS OF MONOISOPINOCAMPHEYLBORANE OF HIGH OPTICAL PURITY
BROWN, HC
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SINGARAM, B
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (22) : 4395 - 4397
[7] BROWN HC, 1975, ORGANIC SYNTHESES VI, P191
[8] DILONGIFOLYLBORANE - A NEW EFFECTIVE CHIRAL HYDROBORATING AGENT WITH INTERMEDIATE STERIC REQUIREMENTS
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (14) : 2988 - 2990
[9] JADHAV PK, UNPUBLISHED
[10] MONOISOPINOCAMPHEYLBORANE - AN EXCELLENT CHIRAL HYDROBORATING AGENT FOR PHENYL-SUBSTITUTED TERTIARY OLEFINS - SYNTHESIS OF ALCOHOLS APPROACHING 100-PERCENT ENANTIOMERIC EXCESS
MANDAL, AK
JADHAV, PK
BROWN, HC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (17) : 3543 - 3544