THE REACTION OF BENZENE WITH DIETHYLAMINE IN THE PRESENCE OF AN IRIDIUM(I) MERCURY(II) BASED SYSTEM - A MODEL ROUTE FOR THE DIRECT AMINATION OF AROMATIC-HYDROCARBONS

被引：16

作者：

DIVERSI, P

ERMINI, L

INGROSSO, G

LUCHERINI, A

PINZINO, C

SAGRAMORA, L

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[2] CNR,IST CHIM QUANTIST & ENERGET MOLEC,I-56126 PISA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 494卷 / 1-2期

关键词：

IRIDIUM; AMINATION; C-H ACTIVATION; N-H ACTIVATION; MERCURY; CATALYSIS;

D O I：

10.1016/0022-328X(94)05391-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N-Diethylaniline is formed under mild conditions either by the direct amination of benzene with diethylamine in the presence of [Ir(eta 5-C(5)Me(5))(CO)(2)] 1 and HgSO4 or by reacting (C6H5)(2)Hg or C6H5HgCl/Ag2SO4 with diethylamine in the presence of 1. A preliminary investigation about the chemistry underlying these reactions is also reported.

引用

页码：C1 / C3

页数：3

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