CHEMISTRY OF POLYFUNCTIONAL LIGANDS .50. CHROMIUM, MOLYBDENUM AND TUNGSTEN CARBONYL-COMPLEXES OF AN ORGANO-CYCLOTRIARSINE

被引：10

作者：

ELLERMANN, J

LINDNER, HA

GABELEIN, H

机构：

[1] Institut für Anorganische Chemie der Universität Erlangen-Nürnberg., D-8520 Erlangen

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 172卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81855-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organocyclotriarsine CH3C(CH2As)3 reacts with Group VI metal hexacarbonyls under ultraviolet irradiation to give the complexes CH3C(CH2As)2M(CO)5 (M = Mo, W), [CH3C(CH2As)3M(CO)4 (M = Cr, W) and [CH3C(CH2As)3Mo- (CO)4]n (2 ≧ 2). The reactions depend mostly on the solvents employed and the molar ratios of the reagents. Starting with C7H8Mo(CO)3 (C7H8 = cycloheptatriene) CH3C(CH2As)3 yields the presumably polymeric complex [CH3C(CH2As)3Mo(CO)3]n. The structures of the compounds are discussed on the basis of their mass, infrared, far infrared and Raman spectra. © 1979.

引用

页码：39 / 56

页数：18

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