A NOVEL PREPARATIVE METHOD FOR HOMOANNULAR AND HETEROANNULAR CONJUGATED DIENES IN DECALIN DERIVATIVES BY THE PALLADIUM-CATALYZED REGIOSELECTIVE ELIMINATION-REACTION OF ALLYLIC CARBONATES UNDER MILD CONDITIONS

被引：14

作者：

MANDAI, T

MATSUMOTO, T

NAKAO, Y

TERAMOTO, H

KAWADA, M

TSUJI, J

机构：

[1] Department of Applied Chemistry, Okayama University of Science, 700, Ridai-cho, Okayama Japan

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

PROVITAMIN-D; ALLYL CARBONATES; PALLADIUM PHOSPHINE COMPLEX CATALYSTS;

D O I：

10.1016/S0040-4039(00)92239-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Homoannular conjugated dienes in decalin systems can be prepared by the palladium-catalyzed elimination reaction of alpha-allylic carbonates, and heteroannular dienes are obtained from beta-allylic carbonates.

引用

页码：2549 / 2552

页数：4