SYNTHESIS AND STRUCTURAL STUDIES OF TETRAAQUACOPPER(II) DIAQUABIS(MALONATO)CUPRATE(II)

被引：74

作者：

CHATTOPADHYAY, D

CHATTOPADHYAY, SK

LOWE, PR

SCHWALBE, CH

MAZUMDER, SK

RANA, A

GHOSH, S

机构：

[1] BENGAL ENGN COLL,DEPT CHEM,HOWRAH 711103,W BENGAL,INDIA

[2] SAHA INST NUCL PHYS,DIV CRYSTALLOG & MOLEC BIOL,CALCUTTA 700064,INDIA

[3] ASTON UNIV,DEPT PHARMACEUT SCI,BIRMINGHAM B4 7ET,ENGLAND

[4] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 06期

关键词：

D O I：

10.1039/dt9930000913

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetraaquacopper(II) diaquabis(malonato)cuprate(II) has been synthesised and its structure determined by X-ray crystallography. Variable-temperature magnetic susceptibility measurements, as well as EPR and UV/VIS spectroscopic studies have also been carried out. The results show that in the solid state the compound exists as a binuclear entity, while in aqueous solution it appears to be mononuclear. This study sets at rest earlier conjectures about the structure of this interesting compound which is also found to exhibit antileukaemic activities in vivo.

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页码：913 / 916

页数：4

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