STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .21. SOLVOLYSIS OF 2-ARYL-2-NORBORNYL AND 2-ARYL-2-CAMPHENILYL PARA-NITROBENZOATES - CRITICAL-EXAMINATION OF IMPORTANCE OF SIGMA-PARTICIPATION IN SOLVOLYSIS TERTIARY 2-NORBORNYL DERIVATIVES BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND

被引：31

作者：

BROWN, HC ^{[1
]}

TAKEUCHI, K ^{[1
]}

RAVINDRANATHAN, M ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1977年 / 99卷 / 08期

关键词：

D O I：

10.1021/ja00450a047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2684 / 2690

页数：7

共 33 条

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[6] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .17. SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL-1-ETHYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER - EFFECT OF SUBSTITUENTS ON CYCLOPROPANE RING - SIGMA CONJUGATION VS SIGMA PARTICIPATION
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[8] UNUSUALLY HIGH EXO ENDO RATE RATIOS IN SOLVOLYSIS OF 2-P-ANISYLCAMPHENILYL AND RELATED COMPOUNDS - FURTHER EVIDENCE FOR STERIC EFFECTS AS A MAJOR FACTOR IN EXO ENDO RATE RATIOS OF TERTIARY NORBORNYL DERIVATIVES
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[10] A CONVENIENT PROCEDURE FOR QUANTITATIVE CONVERSION OF REACTIVE ALCOHOLS AND OLEFINS INTO CORRESPONDING CHLORIDES
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