REACTIONS OF T-BUTYL PEROXIDE WITH PHENOLS

被引：18

作者：

JOHNSTON, KM

JACOBSON, RE

WILLIAMS, GH

机构：

[1] Department of Chemistry, The Polytechnic

[2] Department of Chemistry, Bedford College (University of London), London

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 10期

关键词：

D O I：

10.1039/j39690001424

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of free radicals, formed by thermal decomposition of t-butyl peroxide, with phenols has been studied Although the major products were 2,2′-dihydroxy-derivatives of biphenyl the isomeric 2-hydoxydiphenyl ethers were also formed. Pummerer's ketone was not formed, and the isolation of 4,4′-dihydroxy-3,3′-dimethylbibenzyl from the reaction with 2,4-dimethylphenol has shown that coupling via benzyl radicals is nrot restrictedto fully hindered phenols or to 4-methoxytoluene.

引用

页码：1424 / &

共 27 条

[1]

BARTON DHR, 1967, CHEM BRIT, V3, P330

[2]

BOWDEN K, 1950, J CHEM SOC, P2249

[3]

CHATTAWAY FD, 1931, J CHEM SOC, P2495

[4] THE OXIDATION OF PHENOLS WITH BENZOYL PEROXIDE .2. [J].

COSGROVE, SL ;

WATERS, WA .

JOURNAL OF THE CHEMICAL SOCIETY, 1951, (FEB) :388-391

[5] THE OXIDATION OF PHENOLS WITH THE FREE HYDORXYL RADICAL [J].

COSGROVE, SL ;

WATERS, WA .

JOURNAL OF THE CHEMICAL SOCIETY, 1951, (JUL) :1726-1730

[6]

FREUND M, 1906, BER, V39, P2235

[7] THE OXIDATION OF MONOHYDRIC PHENOLS BY ALKALINE FERRICYANIDE [J].

HAYNES, CG ;

TURNER, AH ;

WATERS, WA .

JOURNAL OF THE CHEMICAL SOCIETY, 1956, (AUG) :2823-2831

[8] OXIDATION OF PHENOLS .I. OXIDATION OF 2,6-DI-T-BUTYL-4-METHYLPHENOL 2,6-DI-T-BUTYLPHENOL AND 2,6-DIMETHYLPHENOL WITH PEROXY RADICALS [J].

HORSWILL, EC ;

INGOLD, KU .

CANADIAN JOURNAL OF CHEMISTRY, 1966, 44 (03) :263-&

[9] EFFECT OF SUBSTITUENTS ON RELATIVE RATES OF REACTION OF TERT-BUTOXY RADICALS WITH PHENOLS IN CARBON TETRACHLORIDE AND IN CHLOROBENZENE [J].

INGOLD, KU .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1963, 41 (11) :2816-&

[10]

INUBISHI Y, 1962, J PHARM SOC JAPAN, V82, P696

← 1 2 3 →