MATRIX INFRARED-SPECTRA OF THE PRODUCTS FROM PHOTOCHEMICAL-REACTIONS OF P-4 WITH O-3 AND DECOMPOSITION OF P4O6

被引：15

作者：

MIELKE, Z ^{[1
]}

ANDREWS, L ^{[1
]}

机构：

[1] UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 15期

关键词：

D O I：

10.1021/ic00340a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The P4/O3 matrix system has been reinvestigated by using dilute P4 and a wide range of photolysis wavelengths. With red photolysis the major product is terminal P4O; with ultraviolet photolysis absorptions for oxo-bridged tetrahedral P4O and cyclic planar P4O plus a series of oxo-bridged absorptions leading to P4O6 and P4O7 dominate. Vacuum ultraviolet photolysis and glow discharge of P4O4 produced an absorption for P4O7 and three absorptions common to the P4/O3 photolysis system, which are assigned to oxo-bridged P4O5, P4O4, and P4O3. © 1990, American Chemical Society. All rights reserved.

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页码：2773 / 2779

页数：7

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