EQUILIBRIUM CONFIGURATION OF ACETIC-ACID

被引：28

作者：

CAMINATI, W

SCAPPINI, F

CORBELLI, G

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

[2] CNR,SPETTROSCOPIA MOLEC LAB,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1979年 / 75卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-2852(79)90126-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The two isotopic species CH2DCOOH and CH2DCOOD of acetic acid have been investigated with microwave spectroscopy in order to determine the equilibrium configuration of the methyl group, which was found to be eclipsed with respect to the carbonyl group. Centrifugal distortion constants free from internal rotation effects have been determined. A rs structure for the four hydrogens and a partial r0 structure for the whole molecule are given. © 1979.

引用

页码：327 / 332

页数：6

共 15 条

[1]

CAMINATI W, 1977, 5 C HIGH RES MOL SPE

[2] DETERMINATION OF STRUCTURE BY ISOTOPIC SUBSTITUTION IN MOLECULES WITH SYMMETRICALLY EQUIVALENT ATOMS [J].