PHOTOLYSIS OF ALKYLHALODIAZIRINES - 2 PATHWAYS FOR VINYL HALIDE FORMATION

被引：44

作者：

LAVILLA, JA ^{[1
]}

GOODMAN, JL ^{[1
]}

机构：

[1] UNIV ROCHESTER,DEPT CHEM,ROCHESTER,NY 14627

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 36期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)97817-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photoacoustic calorimetry and product studios on the photochemical decomposition of methylhalodiazirines indicate two pathways for the formation of vinyl halides: 1) a [1,2] intramolecular hydrogen shift of the initially formed methylhalocarbene, 2) an excited state pathway which circumvents the ground state carbene. Results suggest that carbene/olefin or carbene/alcohol complexes are not involved in vinyl halide formation. © 1990.

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页码：5109 / 5112

页数：4

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