CRYSTAL-STRUCTURES OF (TRIS(TRIMETHYLSILYL)METHYL)POTASSIUM AND (TRIS(DIMETHYLPHENYLSILYL)METHYL)POTASSIUM

被引：73

作者：

EABORN, C ^{[1
]}

HITCHCOCK, PB ^{[1
]}

IZOD, K ^{[1
]}

JAGGAR, AJ ^{[1
]}

SMITH, JD ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 03期

关键词：

D O I：

10.1021/om00015a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of (RMe2Si)3CK (R = Me, 1; R = Ph, 2), obtained from MeK and (RMe2Si)3CH, contain linear chains of alternate potassium cations and planar [(RMe2Si)3C]- anions, with weak interactions between chains; in 1 the central carbon atoms of the anions are midway between the potassium cations, but in 2 cation-anion pairs are linked by eta6 coordination of phenyl groups.

引用

页码：753 / 754

页数：2

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