Reaction of arsenic(III) oxide, arsenous and arsenic acids with thiols

被引：49

作者：

Serves, SV

Charalambidis, YC

Sotiropoulos, DN

Ioannou, PV

机构：

[1] Department of Chemistry, University of Patras, Patras

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1995年 / 105卷 / 1-4期

关键词：

arsenic(III) oxide; arsenous acid; arsenic acid; triaryl trithioarsenites; trialkyl trithioarsenites;

D O I：

10.1080/10426509508042053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Arsenic(III) oxide and arsenous acid in water or aqueous ethanolic solutions react, at room temperature, with a variety of lipophilic and hydrophilic thiols giving quantitatively triaryl and trialkyl trithioarsenites, (ArS)(3)As and (RS)(3)As. Aqueous solutions of arsenic acid react with certain thiols giving quantitatively mixtures of trithioarsenites and disulfides, RSSR. These reactions may help towards the elucidation of the biochemistry of arsenous and arsenic acids.

引用

页码：109 / 116

页数：8

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