SEPARATION OF MOLYBDENUM AND RHENIUM BY EXTRACTION WITH MIXTURES OF TRIOCTYLAMINE AND ALIQUAT 336 FOLLOWED BY SELECTIVE STRIPPING

被引：53

作者：

KARAGIOZOV, L ^{[1
]}

VASILEV, C ^{[1
]}

机构：

[1] GRAD CHEM TECHNOL INST,DEPT NONFERROUS MET,SOFIA 56,BULGARIA

来源：

HYDROMETALLURGY | 1979年 / 4卷 / 01期

关键词：

D O I：

10.1016/0304-386X(79)90005-7

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Molybdenum and rhenium may be co-extracted from acidic media by a mixture of trioctylamine (3.2-4.5%) and Aliquat 336 (0.5-1.8%) in kerosene/5% iso-octanol. Molybdenum can be selectively stripped by ammonia or ammonium salts to give an aqueous phase containing 60 g/l Mo and 0.01 g/l Re. Rhenium may then be stripped from the resulting organic phase with 8 M nitric acid to give an aqueous solution containing 7 g/l Re and 0.15 g/l Mo. © 1979.

引用

页码：51 / 55

页数：5

共 8 条

[1]

Goshoi, Zibby, The Distribution of the Subgroup VII Elements between Pyridine and 4 N NaOH1, Journal of the American Chemical Society, 74, (1952)

[2]

Zelikman, Nerezov, Zvetnie Metali, 1, (1968)

[3]

Churward, Rosebaum, Metals, 15, (1963)

[4]

Paatero, Acta Acad. Aboen., 34 B, 1, (1974)

[5]

Ryabchikov, Lazarev, Renii, Acad. Sci. USSR, (1961)

[6]

Pavlova, Zh. Anal. Khimii, 25, (1970)

[7]

Geilmann, Bode, Anal. Chem., 133, (1951)

[8]

Selikman, Molibden. Izd. Metalurgia, (1970)

← 1 →