CRYSTAL-STRUCTURE AND TWINNING BEHAVIOR OF FERRIC MOLYBDATE, FE2(MOO4)3

被引:107
作者
CHEN, HY
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D O I
10.1016/0025-5408(72)90228-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fe2(MoO4)3 is monoclinic, space group P21 a with a = 15.707, b = 9.231, c = 18.204 A ̊ and β = 125.25°. The structure was solved by the direct method and Fourier technique, and refined by least squares to an R = 0.028. The structure contains isolated MoO4 tetrahedra and FeO6 octahedra, which share corners. The rather open structure shows apparent flexibility and an ease to twinning. The twinning behavior is related to the pseudosymmetry and the ferroelastic transition. © 1979.
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页码:1583 / 1590
页数:8
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