HEAT OF SOLUTION OF CHOLESTEROL AND ITS INTERACTIONS WITH DIFFERENT SOLVENTS - A CALORIMETRIC STUDY

被引：10

作者：

GORALSKI, P ^{[1
]}

TKACZYK, M ^{[1
]}

BRAJTBURG, J ^{[1
]}

机构：

[1] WASHINGTON UNIV,SCH MED,DEPT MED,DIV INFECT DIS,ST LOUIS,MO 63130

来源：

THERMOCHIMICA ACTA | 1990年 / 165卷 / 01期

关键词：

D O I：

10.1016/0040-6031(90)80205-D

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The values of the standard enthalpy of solution of cholesterol (ΔHsXXX) in twelve solvents of various polarities and with different proton-acceptor and proton-donor properties were measured by calorimetry. The enthalpies of the cholesterol interaction and solvation in these media relative to cyclohexane were evaluated. Among the discussed factors affecting the solute-solvent interaction (dispersion, dipole and donor-acceptor interactions), the dispersion forces characterised by the Hildebrand solubility parameter was found to play a considerable role. © 1990.

引用

页码：49 / 55

页数：7

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