CONTROLLED RATE EVOLVED GAS-ANALYSIS - RECENT EXPERIMENTAL SET-UP AND TYPICAL RESULTS

被引：39

作者：

ROUQUEROL, J ^{[1
]}

BORDERE, S ^{[1
]}

ROUQUEROL, F ^{[1
]}

机构：

[1] UNIV AIX MARSEILLE 1,F-13331 MARSEILLE 3,FRANCE

来源：

THERMOCHIMICA ACTA | 1992年 / 203卷

关键词：

D O I：

10.1016/0040-6031(92)85196-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The equipment described is designed for the study of complex thermal decompositions. The heating of the sample is carried out under conditions of controlled transformation rate thermal analysis (CRTA) to enhance the information obtained from the computerized quadrupole gas analyser (especially, but not only, by improving the separation between steps). It operates between -20 and +1000-degrees-C. The thermolysis of hexahydrated nickel nitrate is briefly examined as an example.

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页码：193 / 202

页数：10

相关论文

共 13 条

[1] ANALYTICAL POSSIBILITIES OF CONTROLLED TRANSFORMATION RATE THERMAL-ANALYSIS - THERMOLYSIS OF HEXAHYDRATE URANYL-NITRATE [J].

BORDERE, S ;

FOURCADE, R ;

ROUQUEROL, F ;

FLOREANCIG, A ;

ROUQUEROL, J .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1990, 87 (7-8) :1233-1248

[2] KINETIC POSSIBILITIES OF CONTROLLED TRANSFORMATION RATE THERMAL-ANALYSIS (CRTA) - APPLICATION TO THE THERMOLYSIS OF HEXAHYDRATED URANYL-NITRATE [J].

BORDERE, S ;

ROUQUEROL, F ;

ROUQUEROL, J ;

ESTIENNE, J ;

FLOREANCIG, A .

JOURNAL OF THERMAL ANALYSIS, 1990, 36 (05) :1651-1668

[3] CORRELATION BETWEEN THE SHAPE OF CONTROLLED-RATE THERMAL-ANALYSIS CURVES AND THE KINETICS OF SOLID-STATE REACTIONS [J].

CRIADO, JM ;

ORTEGA, A ;

GOTOR, F .

THERMOCHIMICA ACTA, 1990, 157 (01) :171-179

[4] SIMULTANEOUS TG-DTA MASS-SPECTROMETRY TO 1550-DEGREES [J].

EMMERICH, WD ;

KAISERSBERGER, E .

JOURNAL OF THERMAL ANALYSIS, 1979, 17 (01) :197-212

[5] MODERN METHODS FOR COUPLING QUADRUPOLE MASS SPECTROMETERS WITH THERMO-ANALYZERS FOR TEMPERATURES UP TO 1500DEGREESC [J].

EPPLER, H ;

SELHOFER, H .

THERMOCHIMICA ACTA, 1977, 20 (01) :45-52

[6]

Friedman H. L., 1970, THERMOCHIM ACTA, V1, P199

[7] THERMAL-ANALYSIS USING MASS-SPECTROMETRY - A REVIEW [J].

MORELLI, JJ .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1990, 18 (01) :1-18

[8]

ORTEGA A, 1990, THERMOCHIM ACTA, V163, P125

[9] MASS-SPECTROMETRIC DETERMINATION OF KINETIC-PARAMETERS FOR SOLID-STATE DECOMPOSITION REACTIONS .1. METHOD - CALCIUM-OXALATE DECOMPOSITION [J].

PRICE, D ;

DOLLIMORE, D ;

FATEMI, NS ;

WHITEHEAD, R .

THERMOCHIMICA ACTA, 1980, 42 (03) :323-332

[10] RECENT DEVELOPMENTS IN THE CALORIMETRIC AND THERMOANALYTICAL APPROACHES TO PROBLEMS RELATED TO FOSSIL-FUELS (GENESIS, EXTRACTION AND USE) [J].

ROUQUEROL, J .

PURE AND APPLIED CHEMISTRY, 1985, 57 (01) :69-77