ENANTIOSELECTIVE MICROBIAL OXIDATION OF 1-ARYLETHANOL IN AN ORGANIC-SOLVENT

被引：16

作者：

NAKAMURA, K

INOUE, Y

OHNO, A

机构：

[1] Institute for Chemical Research Kyoto University, Uji, Kyoto

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)73359-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactivity in enantioselective oxidation of 1-arylethanol by Geotrichum candidum is improved when the microbe is entrapped with a water-adsorbent polymer and the reaction is conducted in hexane. Cyclohexanone as an additive improves the rate of oxidation as well as ee of the remained alcohol.

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页码：4375 / 4376

页数：2

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