AROMATIC HYDROCARBON DERIVATIVES OF FULLERENES

被引：30

作者：

HOKE, SH ^{[1
]}

MOLSTAD, J ^{[1
]}

PAYNE, GL ^{[1
]}

KAHR, B ^{[1
]}

BENAMOTZ, D ^{[1
]}

COOKS, RG ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1991年 / 5卷 / 10期

关键词：

D O I：

10.1002/rcm.1290051010

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The fullerenes C60 and C70 form adducts with toluene, p-xylene and other aromatic compounds when refluxed in these solvents in the presence of FeCl3. Benzene derivatives are produced only when bromine is also present. Mass spectra of the reaction mixtures indicate the presence of derivatives including 1:1 adducts, as well as products of multiple additions of the aromatic molecules and their dehydrogenation products. Tandem mass spectrometry provides evidence for C-C bond formation between the adducts and fullerenes.

引用

页码：472 / 474

页数：3

共 18 条

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