SYNTHESIS AND CHARACTERIZATION OF NEW WATER-SOLUBLE TERTIARY PHOSPHINES HAVING TERMINALLY SUBSTITUTED ALKYLENE SULFONATE OR ALKYLENE PHOSPHONATE CHAINS

被引：56

作者：

GANGULY, S ^{[1
]}

MAGUE, JT ^{[1
]}

ROUNDHILL, DM ^{[1
]}

机构：

[1] TULANE UNIV,DEPT CHEM,NEW ORLEANS,LA 70118

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 17期

关键词：

D O I：

10.1021/ic00043a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tertiary phosphine [Ph2PCH2CH2SO3-]Na+ has been prepared by reacting Ph2PNa with [BrCH2CH2SO3-]Na+. For[Ph2PCH2CH2P(O)O22-] Na+2 the synthetic procedure involves treating Ph2PLi with BrCH2CH2P(O)(OEt)2 followed by hydrolysis of the intermediate Ph2PCH2CH2P(O)(OEt)2 using BrSiMe3. This intermediate compound is confirmed by the single-crystal structure of trans-PdBr2(Ph2PCH2CH2P(O)(OEt)2)2.

引用

页码：3500 / 3501

页数：2

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