SOLVENT-INDUCED INVERSION OF ENANTIOSELECTIVITY IN LIPASE-CATALYZED ESTERIFICATION OF 2-PHENOXYPROPIONIC ACIDS

被引:51
作者
UEJI, S [1 ]
FUJINO, R [1 ]
OKUBO, N [1 ]
MIYAZAWA, T [1 ]
KURITA, S [1 ]
KITADANI, M [1 ]
MUROMATSU, A [1 ]
机构
[1] KONAN UNIV,FAC SCI,DEPT CHEM,KOBE 658,JAPAN
关键词
D O I
10.1007/BF01023352
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
In the esterification of 2-phenoxypropionic acids catalyzed by Candida cylindracea lipase, its enantioselectivity was inverted in non-polar solvents such as carbon tetrachloride from that in polar solvents such as acetone. A model for this inversion is suggested.
引用
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页码:163 / 168
页数:6
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