SOLVENT-INDUCED INVERSION OF ENANTIOSELECTIVITY IN LIPASE-CATALYZED ESTERIFICATION OF 2-PHENOXYPROPIONIC ACIDS

被引：51

作者：

UEJI, S ^{[1
]}

FUJINO, R ^{[1
]}

OKUBO, N ^{[1
]}

MIYAZAWA, T ^{[1
]}

KURITA, S ^{[1
]}

KITADANI, M ^{[1
]}

MUROMATSU, A ^{[1
]}

机构：

[1] KONAN UNIV,FAC SCI,DEPT CHEM,KOBE 658,JAPAN

来源：

BIOTECHNOLOGY LETTERS | 1992年 / 14卷 / 03期

关键词：

D O I：

10.1007/BF01023352

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

In the esterification of 2-phenoxypropionic acids catalyzed by Candida cylindracea lipase, its enantioselectivity was inverted in non-polar solvents such as carbon tetrachloride from that in polar solvents such as acetone. A model for this inversion is suggested.

引用

页码：163 / 168

页数：6

共 9 条

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