DIRECT AND STEREOSELECTIVE PREPARATION OF OPTICALLY-ACTIVE 1,3-DIOXOLANES FROM THE CORRESPONDING CHIRAL STYRENE OXIDES

被引：26

作者：

NAGATA, T

TAKAI, T

YAMADA, T

IMAGAWA, K

MUKAIYAMA, T

机构：

[1] MITSUI PETROCHEM IND CO LTD, BASIC RES LABS ORGAN SYNTHESIS, CHIBA 29902, JAPAN

[2] SCI UNIV TOKYO, FAC SCI, DEPT APPL CHEM, SHINJUKU KU, TOKYO 162, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 09期

关键词：

D O I：

10.1246/bcsj.67.2614

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of titanium(IV) chloride, optically active styrene oxide and its analogs are directly converted into the corresponding acetals such as acetonides or cyclopentylidene acetals keeping up high to complete optical purity on the treatment with ketones.

引用

页码：2614 / 2616

页数：3

共 20 条

[1] ENANTIOSELECTIVE SYNTHESES USING CHIRAL EPOXY-ALCOHOLS [J].