SYNTHESIS OF PERFLUORO (ALKYLETHERPHENYL) PHOSPHINES

被引：8

作者：

GOPAL, H

SNYDER, CE

TAMBORSKI, C

机构：

[1] Air Force Materials Laboratory, Wright-Patterson Air Force Base

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1979年 / 14卷 / 06期

关键词：

D O I：

10.1016/S0022-1139(00)82526-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first perfluorophenyl substituted phosphine, C6F5)3P was prepared by Wall et al. [1]. Since then numerous pentafluorophenylphosphorous compounds [2] have been prepared and their properties studied. Substituted perfluorophenylphosphines (RfC6F4)3P however not been extensively studied. Those that have been reported are all solids: (C6F5)3P, m.p. 116° [1]; (p-CF3C6F4)3P, m.p. 103-105° [3]; (p-C8F17C6F4)3P m.p. 117° [3]; and (p-C6F5OC6F4)3P, m.p. 135-137° [4]. © 1979.

引用

页码：511 / 518

页数：8

共 10 条

[1]

BUXTON MW, 1972, J FLUORINE CHEM, V2, P231

[2] SYNTHESIS AND REACTIONS OF ORGANOLITHIUM AND -MAGNESIUM COMPOUNDS OF PERFLUORODIPHENYL ETHERS [J].