ROLE OF COORDINATED HYDROXIDE ION IN CONFIGURATIONAL CONVERSIONS OF TETRAAMINE MACROCYCLIC LIGAND COMPLEXES OF COPPER(II)

被引：62

作者：

LIANG, BF

MARGERUM, DW

CHUNG, CS

机构：

[1] NATL TSINGHUA UNIV,DEPT CHEM,HSINCHU,TAIWAN

[2] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1021/ic50197a056

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Blue-to-red interconversion of the copper(II) complex of tet b (II) is base catalyzed due to the required inversion of nitrogen atoms in the complexes. Coordinated hydroxide ion is much more reactive than free hydroxide ion and a concerted mechanism is proposed in which intramolecular hydrogen bonding, nitrogen inversion, and ring conformational changes occur. © 1979, American Chemical Society. All rights reserved.

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页码：2001 / 2007

页数：7

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