SELECTIVE ACETYLATION OF PORPHYRINS POSSESSING A FREE PYRROLIC POSITION AS A TOOL FOR PETROPORPHYRIN ANALYSIS - A REINVESTIGATION

被引：11

作者：

JEANDON, C ^{[1
]}

BAUDER, C ^{[1
]}

CALLOT, HJ ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST CHIM,CNRS,URA 31,1 RUE BLAISE PASCAL,F-67008 STRASBOURG,FRANCE

来源：

ENERGY & FUELS | 1990年 / 4卷 / 06期

关键词：

D O I：

10.1021/ef00024a009

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Friedel-Crafts acetylation of petroporphyrins is a useful method for discriminating between fully and partially alkylated macrocycles (pyrrolic positions). A reinvestigation of this reaction led to a better understanding of its course and to a optimization of the conditions, as a function of the complexed metal (nickel or vanadium). © 1990, American Chemical Society. All rights reserved.

引用

页码：665 / 667

页数：3

共 14 条

[1]

BROCKMANN H, 1968, LIEBIGS ANN CHEM, V718, P148

[2]

BUCHLER JW, 1988, LIEBIGS ANN CHEM, P43

[3] A NOVEL METHOD OF FUNCTIONALIZING THE ETHYL CHAIN OF OCTAETHYLPORPHYRIN [J].

CHANG, CK ;

SOTIRIOU, C .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (05) :926-929

[4] 3,8,17-TRIETHYL-2,7,12,18-TETRAMETHYLPORPHYRIN - A WIDELY OCCURRING PIGMENT OF CHLOROPHYLL ORIGIN [J].

CHICARELLI, MI ;

WOLFF, GA ;

MAXWELL, JR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (11) :723-724

[5] A NATURALLY-OCCURRING, CHLOROPHYLL-B RELATED PORPHYRIN [J].

CHICARELLI, MI ;

MAXWELL, JR .

TETRAHEDRON LETTERS, 1984, 25 (41) :4701-4704

[6] CHEMISTRY OF PYRROLIC COMPOUNDS .14. MESO-HYDROXYPROTOPORPHYRIN(IX) AND ITS DERIVATIVES [J].

CLEZY, PS ;

LIEPA, AJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (12) :2477-&

[7]

FISCHER H, 1937, CHEM PYRROLS, V2, P297

[8]

FISCHER H, 1929, LIEBIGS ANN, V468, P108

[9]

FUHRHOP JH, 1975, PORPHYRINS METALLOPO, P648

[10]

FUHRHOP JH, 1978, PORPHYRINS, V2, P145

← 1 2 →