REVERSIBLE HALF-WAVE POTENTIALS OF REDUCTION PROCESSES ON NITROXIDE RADICALS

被引：72

作者：

KATO, Y

SHIMIZU, Y

LIN, YJ

UNOURA, K

UTSUMI, H

OGATA, T

机构：

[1] YAMAGATA UNIV,FAC SCI,DEPT CHEM,YAMAGATA 990,JAPAN

[2] YAMAGATA UNIV,FAC ENGN,DEPT MAT SCI & ENGN,YONEZAWA,YAMAGATA 992,JAPAN

[3] KYUSHU UNIV,FAC PHARMACEUT SCI,DEPT PHYSICOCHEM,FUKUOKA 812,JAPAN

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 17期

关键词：

REDOX POTENTIAL; NITROXIDE RADICAL; HYDROXYLAMINE; CYCLIC VOLTAMMETRY; REDUCTION PROCESS;

D O I：

10.1016/0013-4686(95)00261-C

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The reversible half-wave potential (E(1/2)(rev)) of the reduction process was determined for six nitroxide radicals by cyclic voltammetry as the midpoint potential between reduction and reoxidation peaks. The variations of E(1/2)(rev) with pH were interpreted as the protonation induced by the one-electron reduction of nitroxide radicals.

引用

页码：2799 / 2802

页数：4

共 10 条

[1] ELECTROCHEMISTRY AND SPECTROELECTROCHEMISTRY OF NITROXYL FREE-RADICALS [J].