CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(N,N,N',N'-TETRAMETHYL-1,4-DIAMINOBENZENIUMYL) [WURSTERS BLUE CATION]-TETRACYANOPLATINATE(II)-MONO-HYDRATE

被引:7
作者
ENDRES, H [1 ]
JENTSCH, W [1 ]
KELLER, HJ [1 ]
MARTIN, R [1 ]
MORONI, W [1 ]
NOTHE, D [1 ]
机构
[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-6900 HEIDELBERG 1,FED REP GER
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1979年 / 34卷 / 02期
关键词
Dimerized Radical Cations; Hydrogen-Bridges to [Pt(CN)[!sub]4[!/sub]][!sup]2-[!/sup;
D O I
10.1515/znb-1979-0203
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title compound crystallizes in the monoclinic space group A 2/m (C32hh) with a = 10.61(3) Å, b = 9.511(5) Å and c = 16.47(5) Å, ß = 124.2(1)° and two formula units in the unit cell. The structure was solved by Patterson and Fourier methods and refined by least squares to R — 0.071 based on 1251 observed intensities. The organic cations are slightly distorted and are arranged in dimers along the crystallographic a-axis. There are “mixed stacks” of the planar [Pt(CN)4]2- units which are separated from each other by the WB22+ dimers along b. There is IR-evidence for the formation of hydrogen bridges between [Pt(CN)4]2- units and the crystal water during the modification change of the compound at room temperature. © 1979, Walter de Gruyter. All rights reserved.
引用
收藏
页码:140 / 144
页数:5
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