CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(N,N,N',N'-TETRAMETHYL-1,4-DIAMINOBENZENIUMYL) [WURSTERS BLUE CATION]-TETRACYANOPLATINATE(II)-MONO-HYDRATE

被引：7

作者：

ENDRES, H ^{[1
]}

JENTSCH, W ^{[1
]}

KELLER, HJ ^{[1
]}

MARTIN, R ^{[1
]}

MORONI, W ^{[1
]}

NOTHE, D ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-6900 HEIDELBERG 1,FED REP GER

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1979年 / 34卷 / 02期

关键词：

Dimerized Radical Cations; Hydrogen-Bridges to [Pt(CN)[!sub]4[!/sub]][!sup]2-[!/sup;

D O I：

10.1515/znb-1979-0203

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound crystallizes in the monoclinic space group A 2/m (C32hh) with a = 10.61(3) Å, b = 9.511(5) Å and c = 16.47(5) Å, ß = 124.2(1)° and two formula units in the unit cell. The structure was solved by Patterson and Fourier methods and refined by least squares to R — 0.071 based on 1251 observed intensities. The organic cations are slightly distorted and are arranged in dimers along the crystallographic a-axis. There are “mixed stacks” of the planar [Pt(CN)4]2- units which are separated from each other by the WB22+ dimers along b. There is IR-evidence for the formation of hydrogen bridges between [Pt(CN)4]2- units and the crystal water during the modification change of the compound at room temperature. © 1979, Walter de Gruyter. All rights reserved.

引用

页码：140 / 144

页数：5

共 24 条

[1] METALLIC DERIVATIVE OF POLYMERIC SULFUR NITRIDE - POLY (THIAZYL BROMIDE), (SNBR0.4)X [J].

AKHTAR, M ;

KLEPPINGER, J ;

MACDIARMID, AG ;

MILLIKEN, J ;

MORAN, MJ ;

CHIANG, CK ;

COHEN, MJ ;

HEEGER, AJ ;

PEEBLES, DL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (13) :473-474

[2] MAGNETIC-PROPERTIES OF SOME ELECTRICALLY CONDUCTING PERYLENE METAL DITHIOLATE COMPLEXES [J].

ALCACER, L ;

MAKI, AH .

JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (17) :1912-1916

[3]

ANDRE JJ, 1976, ANN PHYS-PARIS, V1, P145

[4]

BOER JLD, 1972, ACTA CRYSTALLOGR B, V28, P839

[5]

BOER JLD, 1972, ACTA CRYSTALLOGR B, V28, P835

[6] N,N,N',N'-TETRAMETHYL-PARA-PHENYLENEDIAMINE RADICAL-CATION (TMPD+) AS A COUNTER ION IN COMPLEXES OF TETRACYANOPLATINATES (II,IV) AND OF THIOCYANATOPLATINATES (II) [J].

ENDRES, H ;

KELLER, HJ ;

MORONI, W ;

NOTHE, D .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1976, 12 (11) :825-829

[7] CRYSTAL AND MOLECULAR-STRUCTURE AND EPR PROPERTIES OF 1-2 RADICAL SALT TETRAAMMINEPLATINUM(II) "7,7,8,8-TETRACYANOQUINODIMETHANIDE, [PT(NH3)4]2+[(TCNQ)2]2- [J].

ENDRES, H ;

KELLER, HJ ;

MORONI, W ;

NOTHE, D ;

DONG, V .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAY) :1703-1705

[8]

ENDRES H, ACTA CRYSTALLOGR

[9] ANIONIC LINEAR-CHAIN IRIDIUM CARBONYL HALIDES [J].

GINSBERG, AP ;

KOEPKE, JW ;

HAUSER, JJ ;

WEST, KW ;

DISALVO, FJ ;

SPRINKLE, CR ;

COHEN, RL .

INORGANIC CHEMISTRY, 1976, 15 (03) :514-519

[10] TETRAKIS(METHYL ISOCYANIDE)PALLADIUM(II) TETRAKIS(7,7,8,8-TETRACYANO-P-QUINODIMETHANE), [PD(CNME)4](TCNQ)4.2MECN - SYNTHESIS, STRUCTURE, AND PHYSICAL-PROPERTIES [J].

GOLDBERG, SZ ;

EISENBERG, R ;

MILLER, JS ;

EPSTEIN, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (17) :5173-5182

← 1 2 3 →