CATIONIC PHOTOPOLYMERIZATION OF CYCLOHEXENE OXIDE

被引：41

作者：

ABUABDOUN, II

AALEALI

机构：

[1] Chemistry Department, King Fahd University of Petroleum and Minerals, Dhahran

来源：

EUROPEAN POLYMER JOURNAL | 1992年 / 28卷 / 01期

关键词：

D O I：

10.1016/0014-3057(92)90239-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Phenacyltriphenyl phosphonium salts containing the anions SbF6- and PF6- are useful photoinitiators for cationic polymerization of cyclohexene oxide; photosenSitiZation by the addition of pyrene and N-methylphenothiazine enhances the rate of polymerization. Experimental results are presented to show the effects of photolysis time, photosensitization, initiator concentration and the anion on the rate of polymerization in dichloromethane at 25-degrees.

引用

页码：73 / 78

页数：6

共 12 条

[1] PHOTOINITIATED POLYMERIZATION OF VINYL MONOMERS BY BENZOPHENONE TERT-BUTYL PERESTERS [J].