SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A CU(I) DIMER OF A TRIS(OXAZOLINE) LIGAND

被引：23

作者：

SORRELL, TN

PIGGE, FC

WHITE, PS

机构：

[1] Department of Chemistry, The University of North Carolina at Chapel Hill, Chapel Hill

来源：

INORGANICA CHIMICA ACTA | 1993年 / 210卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0020-1693(00)82827-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new tripodal tris(oxazoline) ligand, tris[4,4-dimethyl-2-(4,5-dihydrooxazolyl)]methylamine is described, and details of the X-ray crystal structure of its Cu(I) complex are presented. The complex crystallizes as a dimer in the triclinic space group P1BAR. Each Cu(I) ion is coordinated in a distorted trigonal geometry by two oxazoline groups from one tripod and a third oxazoline from the second ligand. The Cu(I)-Cu(I) distance is 5.7 angstrom. The CO adduct of the complex exhibits v(CO)=2066 cm-1.

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页码：87 / 90

页数：4

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