POLYALKYLATED AROMATIC MONOMERS AND POLYMERS .1. FRIEDEL-CRAFTS DIACYLATION OF POLYMETHYLBENZENES AS A MEANS OF MONOMER SYNTHESIS

被引：7

作者：

HENDY, BN ^{[1
]}

PATTERSON, KH ^{[1
]}

SMITH, DM ^{[1
]}

GARDNER, SE ^{[1
]}

NICOLSON, NJ ^{[1
]}

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 02期

关键词：

D O I：

10.1039/jm9950500199

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Diacylation of mesitylene, durene and isodurene by the Friedel-Crafts method, using the acylating agent in excess (as both solvent and reagent), gives derivatives which are of potential use as monomers. The bis(p-fluorobenzoyl) derivatives, for example, can function as the electrophilic components in poly(ether ether ketone) (PEEK)-type polymerisations, and the bisnitrobenzoyl compounds are potential sources of novel diamines. Tribenzoylation [although not tris(p-fluorobenzoylation)] of mesitylene has been observed, but dibenzoylation of m-xylene is a much less efficient process than previously reported.

引用

页码：199 / 204

页数：6

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