THIOPHENE CONTAINING SCHIFF-BASES OLIGOMERS AND POLYMERS - SYNTHESIS, CHARACTERIZATION AND PROPERTIES

被引：31

作者：

AMARI, C ^{[1
]}

PELIZZI, C ^{[1
]}

PREDIERI, G ^{[1
]}

DESTRI, S ^{[1
]}

PORZIO, W ^{[1
]}

机构：

[1] UNIV PARMA,DIPARTIMENTO CHIM GEN & INORGAN CHIM ANAL CHIM FI,VIALE SCI,I-43100 PARMA,ITALY

来源：

SYNTHETIC METALS | 1995年 / 72卷 / 01期

关键词：

THIOPHENE; SCHIFF BASES; SYNTHESIS; OLIGOMERS;

D O I：

10.1016/0379-6779(94)02310-U

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

By reaction of the 2,5-dicarboxaldehyde and certain 2,5-diketo derivatives of thiophene and 3-alkylthiophenes with hydrazine in toluene, we have obtained a new family of air-stable polymeric azines. Oligomers and polymers were separated by extraction with different solvents and characterized by molecular weight determinations, vibrational and electronic spectroscopy and thermal analysis. A major feature of the polymers containing butyl groups is their complete solubility, the other materials being insoluble in the common solvents to a large extent.

引用

页码：7 / 12

页数：6

共 34 条

[1] BACCHETTI T, 1953, GAZZ CHIM ITAL, V83, P823
[2] IMINYL RADICALS IN GAS-PHASE SYNTHESIS .1. GENERATION OF NITRILES BY PYROLYSIS OF ARYL AZINES
BIRD, KJ
CHAN, AWK
CROW, WD
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (10) : 2281 - 2287
[3] BRADLEY DDC, 1992, SPRINGER SERIES SOLI, V107, P304
[4] POLYMERS FOR NONLINEAR OPTICS
BUCKLEY, A
[J]. ADVANCED MATERIALS, 1992, 4 (03) : 153 - 158
[5] MOLECULAR CONFORMATION OF BENZYLIDENEANILINES - RELATION TO ELECTRONIC STRUCTURE AND SPECTRA
BURGI, HB
DUNITZ, JD
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (09): : 472 - &
[6] BUUHOI NP, 1967, B SOC CHIM FR, P955
[7] BUUHOI NP, 1968, B SOC CHIM FR, P2489
[8] STRUCTURE OF GLYOXAL DIHYDRAZONE AND SYNTHESIS, CHARACTERIZATION, AND IODINE DOPING OF UNSUBSTITUTED POLYAZINE
CHALONERGILL, B
CHEER, CJ
ROBERTS, JE
EULER, WB
[J]. MACROMOLECULES, 1990, 23 (21) : 4597 - 4603
[9] DIRECT EVIDENCE OF A BIPOLARON CHARGE CARRIER IN CONDUCTING POLYAZINES FROM C-13 AND N-15 SOLID-STATE NMR-SPECTROSCOPY - DETECTION OF A NITRENIUM CATION BY NATURAL ABUNDANCE N-15 SOLID-STATE NMR-SPECTROSCOPY
CHALONERGILL, B
EULER, WB
MUMBAUER, PD
ROBERTS, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) : 6831 - 6834
[10] ELECTRICALLY CONDUCTING ACETYLENE-METHYLACETYLENE CO-POLYMERS - SYNTHESIS AND PROPERTIES
CHIEN, JCW
WNEK, GE
KARASZ, FE
HIRSCH, JA
[J]. MACROMOLECULES, 1981, 14 (03) : 479 - 485

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