BIS(DIMETHYLMETAL)-N,N',N'',N'''-TETRAMETHYLOXAMIDINES OF ALUMINUM, GALLIUM AND INDIUM - SYNTHESIS, SPECTRA AND X-RAY STRUCTURES

被引：30

作者：

GERSTNER, F ^{[1
]}

SCHWARZ, W ^{[1
]}

HAUSEN, HD ^{[1
]}

WEIDLEIN, J ^{[1
]}

机构：

[1] UNIV STUTTGART,INST ANORGAN CHEM,D-7000 STUTTGART 80,FED REP GER

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 175卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)82297-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N′,N″,N‴-Tetramethyloxamidine, (HNMe)2C2(NMe)2, reacts with the trimethyl derivatives of Al, Ga and In, respectively, in a 1 2 molar ratio. Monomeric bis(dimethylmetal)oxamidines, [Me2M]2C2(NMe)4 with M = Al, Ga, In, and methane are formed. According to the vibrational spectra (IR and Raman) and the X-ray structure determinations of all three compounds these molecules consist of two fused five-membered rings, with an essentially planar structure. The results in the homologous series [Me2M]2C2O4-x(NMe)x (x = 0, 2 and 4 and M = Ga) are compared. © 1979.

引用

页码：33 / 47

页数：15

共 22 条

[1] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].

CROMER, DT ;

MANN, JB .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&

[2]

CROMER DT, 1974, INT TABLES XRAY CRYS, V4, P771

[3]

FISCHER P, 1978, J ORGANOMET CHEM, V144, P95

[4] CONFIGURATIONAL ISOMERISM IN BIS(DIMETHYL METAL)-N,N'-DIALKYLOXAMIDES OF ALUMINUM AND GALLIUM [J].

FISCHER, P ;

GRAF, R ;

STEZOWSKI, JJ ;

WEIDLEIN, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :6131-6132

[5] N,N'-DIMETHYLACETAMIDIN DERIVATIVES OF ALUMINUM, GALLIUM AND INDIUMS [J].

GERSTNER, F ;

WEIDLEIN, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (01) :24-29

[6]

GRAF R, UNPUBLISHED

[7] CRYSTAL AND MOLECULAR-STRUCTURES OF DIMETHYLALUMINUM-N,N'-DIMETHYLACETAMIDINE AND DIMETHYLGALLIUM-N,N'-DIMETHYLACETAMIDINE DIMERS [(CH3)2M(NCH3)2CCH3]2 (M=AL,GA) [J].

HAUSEN, HD ;

GERSTNER, F ;

SCHWARZ, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 145 (03) :277-284

[8] MOLECULAR AND CRYSTAL-STRUCTURE OF BIS-(DIMETHYLGALLIUM) OXALATE,[(CH3)2GA]2C2O4 [J].

HAUSEN, HD ;

MERTZ, K ;

WEIDLEIN, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 67 (01) :7-18

[9]

JOHNSON CK, 1965, ORNL3794 ORT REP

[10] SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE OF A STABLE MONOMERIC 5-CO-ORDINATE GALLIUM-AMINE COMPLEX, CHLORO(DIMETHYL)-1,10-PHEN-ANTHROLINEGALLIUM(III) [J].

MCPHAIL, AT ;

MILLER, RW ;

PITT, CG ;

GUPTA, G ;

SRIVASTAVA, SC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (17) :1657-1661

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