SYNTHESIS AND CHARACTERIZATION OF POLY(N-BUTYL-3,6-CARBAZOLEDIYL) - A NEW SOLUBLE ELECTROACTIVE MATERIAL

被引：30

作者：

NGBILO, E ^{[1
]}

ADES, D ^{[1
]}

CHEVROT, C ^{[1
]}

SIOVE, A ^{[1
]}

机构：

[1] UNIV PARIS 13,RECH MACROMOLEC LAB,CNRS,AVE JB CLEMENT,F-93430 VILLETANEUSE,FRANCE

来源：

POLYMER BULLETIN | 1990年 / 24卷 / 01期

关键词：

D O I：

10.1007/BF00298316

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly (N-butyl-3,6-carbazolediyl) was synthesized by electrochemcial reduction of the NiBr2, 2,2′bipyridine/3,6 dibromo N-butylcarbazole system in N,N dimethylacetamide. The favorable interactions between solvent and butyl groups lead to the solubilization of the electroactive polymer in organic medium and allowed the determination of macromolecular and structural features by means of classical methods. From 13C NMR investigations it was concluded to a Π conjugation centered on the nitrogen atom of the carbazolic structure. © 1990 Springer-Verlag.

引用

页码：17 / 22

页数：6

共 7 条

[1]

ABOULKASSIM A, 1988, J CHIM PHYS PARIS

[2] ELECTRONIC-STRUCTURE OF COPOLYMERS BASED ON PHENYLENE AND THIOPHENE UNITS [J].

CZERWINSKI, W ;

NUCKER, N ;

FINK, J .

SYNTHETIC METALS, 1988, 25 (01) :71-77

[3]

FAUVARQUE JF, 1987, MAKROMOL CHEM, V188, P1833

[4]

JEN KY, 1986, J CHEM SOC CHEM COMM, P1364

[5] STRUCTURAL EFFECT ON THE ELECTROCHEMICAL PROPERTIES OF POLYTHIOPHENE AND DERIVATIVES [J].

TOURILLON, G ;

GARNIER, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 161 (01) :51-58

[6]

ZHONG XF, 1988, MAKROMOL CHEM-RAPID, V9, P411

[7]

1988, IN PRESS SYNTHE 0626

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